Synthesis and characterisation of tetramethylfulvene complexes of ruthenium.

نویسندگان

  • Andrea Rodríguez-Bárzano
  • A John Blacker
  • Patrick C McGowan
چکیده

Reactions of [RuCp*Cl2]2 with dibenzoylmethane and triethylamine, in either dichloromethane or toluene, produced the complexes [RuCl(η(6)-C5Me4CH2)(PhCOCCOPh)] (1) and [RuCl3(η(6)-C5Me4CH2)][RuCp*(C6H5CH3)] (2) respectively under mild conditions. Both compounds 1 and 2 are examples of an unusual tetramethylfulvene-ruthenium structure, obtained by deprotonation of the pentamethylcyclopentadienyl ligand, and were characterised by single-crystal X-ray diffraction.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 48  شماره 

صفحات  -

تاریخ انتشار 2013